Publications
22) McCallum*, T. Heart of gold: enabling ligands for oxidative addition of haloorganics in Au(I)/Au(III) catalysed cross-coupling reactions. Org. Biomol. Chem. 2023, 21, 1629-1646.
Invited Contribution
21) McCallum*, T. Emerging radical rearrangement reactions: The 1,2-boron shift. Green Synth. & Catal. 2023, 4, 10-19.
Invited Contribution
20) Zhong, J.; Ding, C.; Kim*, H.; McCallum*, T.; Ye*, K. Alternating Current Electrolysis: A Photoredox Catalysis Mimic and Beyond. Green Synth. & Catal. 2022, 3, 4-10.
19) Lu, J.; Wang, Y.; McCallum*, T.; Fu,* N. Harnessing Radical Chemistry via Electrochemical Transition Metal Catalysis. iScience. 2020, 23, 101796.
Invited Contribution
18) Zidan, M.; McCallum, T.; Swann, R.; Barriault. Formal Bromine Atom Transfer Radical Addition of Nonactivated Bromoalkanes Using Photoredox Gold Catalysis. Org. Lett. 2020, 22, 8401–8406.
17) Zidan, M.; Morris, A. O.; McCallum, T.; Barriault, L. The Alkylation and Reduction of Heteroarenes with Alcohols using Photoredox Catalyzed Hydrogen Atom Transfer Via Chlorine Atom Generation. Eur. J. Org. Chem. 2020, 1453-1458.
Invited Contribution for Special Issue on Photochemical Synthesis and Highlighted in ChemPhotoChem
16) McCallum, T.; Wu, X.; Lin, S. Recent Advances in Titanium Radical Redox Catalysis. J. Org. Chem. 2019, 84, 14369-14380.
Invited Contribution
15) Ye, K.-Y.;+ McCallum, T.;+ Lin, S. Bimetallic Radical Redox-Relay Catalysis for the Isomerization of Epoxides to Allylic Alcohols. J. Am. Chem. Soc. 2019, 141, 9548-9554.
+Contributed Equally
14) Zidan, M.;+ Rohe, S.;+ McCallum, T.; Barriault, L. Recent advances in mono and binuclear gold photoredox catalysis. Catal. Sci. Technol. 2018, 8, 6019-6028.
+Contributed Equally
Invited Contribution
13) Rohe, S.;+ Morris, A. O.;+ McCallum, T.;+ Barriault, L. Hydrogen Atom Transfer Reactions Via Photoredox Catalyzed Chlorine Atom Generation. Angew. Chem. Int. Ed. 2018, 57, 15664-15569.
+Contributed Equally
Highlighted on Cover
12) Rohe, S.; McCallum, T.; Morris, A. O.; Barriault, L. Transformations of Isonitriles with Bromoalkanes Using Photoredox Gold Catalysis. J. Org. Chem. 2018, 83, 10015-10024.
11) McCallum, T., Pitre, S. P., Morin, M., Scaiano, J. C., Barriault, L. The photochemical alkylation and reduction of heteroarenes. Chem. Sci.. 2017, 8, 7412-7418.
10) Zidan, M., McCallum, T., Thai-Savard, L., Barriault, L. Photoredox meets gold Lewis acid catalysis in the alkylative semipinacol rearrangement: A photocatalyst with a dark side. Org. Chem. Front. 2017, 4, 2092-2096.
Invited Contribution for the themed collection: Synthetic Approaches to Natural Products via Catalytic Processes
Most-Viewed Hot Article of August 2017, Highlighted on Cover
9) McCallum, T., Rohe, S., Barriault, L. Thieme Chemistry Journal Awardees – Where Are They Now? What’s Golden: Recent Advances in Organic Transformations Using Gold Photoredox Catalysis. Synlett 2017, 28, 289-305.
Invited Contribution
8) Tran, H., McCallum, T., Morin, M., Barriault, L. Homocoupling of Iodoarenes and Bromoalkanes using Photoredox Gold Catalysis: A Light Enabled Au(III) Reductive Elimination. Org. Lett. 2016, 18, 4308-4311.
7) McCallum, T., Barriault, L. Direct alkylation of heteroarenes with unactivated bromoalkanes using photoredox gold catalysis. Chem. Sci. 2016, 7, 4754-4758.
6) McCallum, T., Jouanno, L.-A., Cannillo, A., Barriault, L. Persulfate Enabled Direct C-H Alkylation of Heteroarenes from Unactivated Ethers. Synlett 2016, 27, 1282-1286.
Highlighted in Cheminform, Synfacts, most read in March 2016
5) McTiernan, C. D., Morin, M., McCallum, T., Scaiano, J. C., Barriault, L. Polynuclear gold(I) complexes in photoredox catalysis: understanding their reactivity through characterization and kinetic analysis. Catal. Sci. Technol. 2016, 6, 201-207.
4) Kaldas, S. J., Cannillo, A., McCallum, T., Barriault, L. Indole Functionalization via Photoredox Gold Catalysis. Org. Lett. 2015, 17, 2864-2866.
Highlighted in Cheminform
3) McCallum, T., Barriault, L. Light-Enabled Synthesis of Anhydrides and Amides. J. Org. Chem. 2015, 80, 2874-2878.
Highlighted in Cheminform
2) McCallum, T., Slavko, E., Morin, M., Barriault, L. Light-Mediated Deoxygenation of Alcohols with a Dimeric Gold Catalyst. Eur. J. Org. Chem. 2015, 81-85.
Highlighted in Cheminform
1) Revol, G., McCallum, T., Morin, M., Gagosz, F., Barriault, L. Photoredox Transformations with Dimeric Gold Complexes. Angew. Chem. Int. Ed. 2013, 52, 13342-13345.
Highlighted in Cheminform
Opinion Pieces
4) Succinct discoveries that inspire. Science 2023, 381, 24-25.
3) Advocacy in brief. Science 2017, 356, 24-25.
2) March for Science: Share your sign. Science 2017, 356, 147.
1) Science in brief. Science 2016, 353, 22-24.